1) Heat vs Temperature
Heat and Temperature are NOT the same thing — this is the #1 confusion for students. Heat is a form of energy (the total kinetic energy of all molecules), while temperature is a measure of the average kinetic energy of molecules.
| Basis | Heat | Temperature |
|---|---|---|
| Definition | Form of energy that flows from hot to cold bodies | Measure of degree of hotness/coldness (avg KE of molecules) |
| Nature | Energy (total KE of all molecules) | Intensity (average KE per molecule) |
| SI Unit | Joule (J) | Kelvin (K) |
| Other units | calorie (1 cal = 4.184 J), kilocalorie | °Celsius, °Fahrenheit |
| Direction of flow | Flows from higher temperature to lower temperature | Determines direction of heat flow |
| Measuring device | Calorimeter | Thermometer |
| Effect of adding | Increases temperature OR changes state | Heat may increase or remain constant (during phase change) |
| Dependence | Depends on mass, specific heat, and temperature change | Does NOT depend on mass or type of substance |
Think of it like money in a bank:
• Heat = total money in the account (depends on account size)
• Temperature = how rich each person is (average per person)
A large ocean has enormous HEAT but low TEMPERATURE. A small hot pan has high TEMPERATURE but less total HEAT.
(A) Kelvin (B) Celsius (C) Joule (D) Watt
Ans: C (heat is a form of energy → measured in Joule)
(A) Total kinetic energy (B) Average kinetic energy (C) Potential energy (D) Heat content
Ans: B (temperature ∝ average KE of molecules)
2) Thermometers
A thermometer is a device used to measure temperature. It works on the principle that substances expand on heating and contract on cooling.
Types of Thermometers
| Type | Working substance | Range | Use |
|---|---|---|---|
| Mercury thermometer | Mercury (silver liquid) | −10°C to 110°C (clinical) −30°C to 350°C (lab) |
Clinical & laboratory use |
| Alcohol thermometer | Alcohol (coloured red/blue) | −80°C to 80°C | Very cold regions (mercury freezes at −39°C) |
| Digital thermometer | Thermistor / electronic sensor | −50°C to 300°C | Modern clinical & industrial |
Construction & Working (Mercury Thermometer)
- A fine, uniform capillary tube with a bulb at one end filled with mercury
- When temperature rises → mercury expands → rises in capillary tube
- When temperature falls → mercury contracts → falls in capillary tube
- The tube is calibrated using fixed points: lower fixed point (ice point = 0°C) and upper fixed point (steam point = 100°C)
- In clinical thermometer: a kink (constriction) prevents mercury from falling back — allows reading after removal
Fixed Points
- Lower fixed point (Ice point): Temperature of pure melting ice at 1 atm pressure = 0°C / 32°F / 273 K
- Upper fixed point (Steam point): Temperature of boiling water at 1 atm pressure = 100°C / 212°F / 373 K
- The interval between them is divided into equal parts (e.g., 100 parts for Celsius)
• Mercury is used because: it's opaque (easy to see), has uniform expansion, doesn't wet glass, high boiling point (357°C), low freezing point (−39°C)
• Alcohol is used in cold regions because it freezes at −115°C (much lower than mercury's −39°C)
(A) Mercury (B) Alcohol (C) Digital (D) Both A and B
Ans: B (alcohol freezes at −115°C, mercury at −39°C)
3) Temperature Scales — Comparison & Conversion
There are three common temperature scales: Celsius, Fahrenheit, and Kelvin. Kelvin is the SI unit and is also called the absolute scale (no negative temperatures).
| Property | Celsius (°C) | Fahrenheit (°F) | Kelvin (K) |
|---|---|---|---|
| Freezing point of water | 0°C | 32°F | 273 K |
| Boiling point of water | 100°C | 212°F | 373 K |
| Number of divisions | 100 | 180 | 100 |
| Absolute zero | −273.15°C | −459.67°F | 0 K |
| SI unit? | No | No | Yes (SI base unit) |
| Used in | Most countries, science | USA, Myanmar, Liberia | Scientific research |
C/100 = (F − 32)/180 = (K − 273)/100
Celsius → Fahrenheit: °F = (°C × 9/5) + 32
Fahrenheit → Celsius: °C = (°F − 32) × 5/9
Celsius → Kelvin: K = °C + 273
Kelvin → Celsius: °C = K − 273
Fahrenheit → Kelvin: K = (F − 32) × 5/9 + 273
• C → F: "Double and add 32" roughly: e.g., 25°C → 25×2 = 50, 50+30 = 80°F (actual: 77°F — close enough for estimates!)
• F → C: "Subtract 32, then halve" roughly
• K and °C: just add/subtract 273 — no complicated math!
C = (F − 32) × 5/9 = (77 − 32) × 5/9 = 45 × 5/9 = 25°C
F = (C × 9/5) + 32 = (30 × 9/5) + 32 = 54 + 32 = 86°F
C = K − 273 = 300 − 273 = 27°C
Let C = F = x
x = (x − 32) × 5/9
9x = 5x − 160
4x = −160
x = −40
∴ −40°C = −40°F (only point where both are equal!)
(A) 100°F (B) 180°F (C) 212°F (D) 273°F
Ans: C (100 × 9/5 + 32 = 212°F)
(A) 0 K (B) 100 K (C) 273 K (D) 373 K
Ans: C (0 + 273 = 273 K)
(A) 0°C (B) −100°C (C) −273°C (D) −200°C
Ans: C (0 K = −273°C)
4) Thermal Expansion
When a substance is heated, its molecules vibrate more and move farther apart → the substance expands. Different materials expand by different amounts. Three types of expansion exist:
A. Linear Expansion (Length)
Change in length of a solid rod when heated. Applies to solids where one dimension is dominant (wires, rods, rails).
ΔL = α × L₀ × ΔT
ΔL = change in length, L₀ = original length, ΔT = temperature change
α = coefficient of linear expansion (unit: K⁻¹ or °C⁻¹)
Final length L = L₀(1 + αΔT)
B. Superficial/Area Expansion (Surface)
Change in area of a solid surface when heated. Applies to sheets, plates, etc.
ΔA = β × A₀ × ΔT
β = coefficient of area (superficial) expansion
β = 2α (relation between coefficients)
Final area A = A₀(1 + βΔT)
C. Cubical/Volumetric Expansion (Volume)
Change in volume of a substance when heated. Applies to solids, liquids, and gases.
ΔV = γ × V₀ × ΔT
γ = coefficient of volume (cubical) expansion
γ = 3α (relation), γ = 3/2 β
Final volume V = V₀(1 + γΔT)
| Type | Symbol | Formula | Applies to | Relation with α |
|---|---|---|---|---|
| Linear | α | ΔL = α L₀ ΔT | Solids (length) | α |
| Area / Superficial | β | ΔA = β A₀ ΔT | Solids (surface) | β = 2α |
| Volume / Cubical | γ | ΔV = γ V₀ ΔT | Solids, liquids, gases | γ = 3α |
Applications of Thermal Expansion
- Bimetallic strip: Two different metals (e.g., brass and invar/steel) bonded together. On heating, they expand by different amounts → strip bends. Used in: thermostats (automatic iron, AC, refrigerator), fire alarms, thermometers
- Expansion gaps in railway tracks: Gaps left between rails to allow expansion in summer → prevents buckling
- Expansion joints in bridges: One end of bridge is fixed, the other rests on rollers to allow expansion/contraction
- Riveting: Hot rivets are used to join metal plates — on cooling, they contract and hold the plates tightly together
- Iron rims on cart wheels: The rim is heated (expands), placed on the wheel, then cools (contracts) → tight fit
- Loose cap on a bottle: Run hot water on the cap → cap expands → opens easily
• Linear (1D) → α
• Area (2D) → β = 2α (think: 2 dimensions)
• Volume (3D) → γ = 3α (think: 3 dimensions)
• For liquids: we measure apparent expansion (in a container) vs real expansion (actual). Real expansion = apparent expansion + expansion of container
ΔL = α L₀ ΔT = (1.2 × 10⁻⁵)(10)(40 − 20)
= (1.2 × 10⁻⁵)(10)(20)
= 1.2 × 10⁻⁵ × 200 = 240 × 10⁻⁵ = 0.0024 m = 2.4 mm
(A) γ = α (B) γ = 2α (C) γ = 3α (D) γ = α/3
Ans: C (γ = 3α — volume has 3 dimensions)
(A) Thermometer (B) Thermostat (C) Barometer (D) Manometer
Ans: B (thermostat — bimetallic strip bends to make/break electrical contact)
5) Anomalous Expansion of Water ⭐
Most substances expand when heated and contract when cooled — their density decreases with increasing temperature. Water is EXCEPTIONAL in the range 0°C to 4°C.
Water has its MAXIMUM DENSITY at 4°C
From 0°C → 4°C: water contracts (density INCREASES)
From 4°C → above: water expands (density DECREASES)
Ice (0°C) is LESS dense than water at 4°C → ICE FLOATS
| Temperature | Behavior | Density |
|---|---|---|
| 0°C (ice) | Solid — open crystal structure | 0.917 g/cm³ (less — floats) |
| 0°C → 4°C | Contracts (water shrinks) | Increases |
| 4°C | Minimum volume | 1.000 g/cm³ (maximum) |
| 4°C → above | Expands normally | Decreases |
Why is this important? — Lakes freeze from top!
- In winter, air temperature drops → surface water cools → becomes denser → sinks (convection currents)
- When water reaches 4°C, it is at maximum density → sinks to bottom
- Surface water continues cooling below 4°C → becomes less dense → stays at top
- At 0°C, surface water freezes into ice → ice is less dense → floats on top
- The ice layer acts as insulator → water below stays at ~4°C → marine life survives
• If water didn't have anomalous expansion, lakes would freeze from the BOTTOM → all aquatic life would die!
• Ice floats on water because ice density (0.917 g/cm³) < water density (1.000 g/cm³)
• This is why icebergs float — about 90% of an iceberg is underwater
(A) 0°C (B) 4°C (C) 100°C (D) −4°C
Ans: B (4°C — anomalous expansion)
(A) Ice is a good conductor (B) Ice layer insulates the water below (C) Fish hibernate (D) Water at bottom is at 0°C
Ans: B (ice insulates → water below remains at ~4°C)
6) Calorimetry & Specific Heat Capacity ⭐
Heat Capacity
The amount of heat required to raise the temperature of a body by 1°C (or 1 K).
Heat Capacity = m × c (unit: J/°C or J/K)
Specific Heat Capacity (c)
The amount of heat required to raise the temperature of 1 kg of a substance by 1°C (or 1 K).
c = Q / (m × ΔT) Unit: J kg⁻¹ °C⁻¹ (or J/kg°C)
Q = m × c × ΔT
Q = heat energy (J or cal)
m = mass (kg or g)
c = specific heat capacity (J/kg°C or cal/g°C)
ΔT = change in temperature (°C or K)
| Substance | Specific Heat (J/kg°C) | Specific Heat (cal/g°C) |
|---|---|---|
| Water | 4186 ≈ 4200 | 1.0 |
| Ice | 2100 | 0.5 |
| Aluminium | 900 | 0.215 |
| Iron/Steel | 450 | 0.107 |
| Copper | 390 | 0.093 |
| Silver | 235 | 0.056 |
| Sand | ~800 | ~0.19 |
| Alcohol | 2400 | 0.58 |
Water has the highest specific heat among common substances (4200 J/kg°C). This means:
• Water heats up slowly (takes lots of energy)
• Water cools down slowly (releases lots of energy)
• This is why coastal areas have moderate climate — sea water absorbs heat in summer, releases in winter
• This is why water is used as coolant in car radiators and in thermal power plants
Principle of Calorimetry
m₁ × c₁ × (T_hot − T_final) = m₂ × c₂ × (T_final − T_cold)
m₁, c₁ = mass and specific heat of hot body
m₂, c₂ = mass and specific heat of cold body
T_final = equilibrium temperature
Assumption: No heat is lost to the surroundings (ideal calorimeter)
2 kg of water at 80°C is mixed with 3 kg of water at 20°C. Find final temperature. (c_water = 4200 J/kg°C)
Heat lost = Heat gained
2 × 4200 × (80 − T) = 3 × 4200 × (T − 20)
2(80 − T) = 3(T − 20)
160 − 2T = 3T − 60
160 + 60 = 5T
T = 220/5 = 44°C
A 0.5 kg iron block at 200°C is placed in 1 kg water at 25°C. Find final temperature.
c_iron = 450 J/kg°C, c_water = 4200 J/kg°C
Heat lost by iron = Heat gained by water
0.5 × 450 × (200 − T) = 1 × 4200 × (T − 25)
225(200 − T) = 4200(T − 25)
45000 − 225T = 4200T − 105000
45000 + 105000 = 4200T + 225T
150000 = 4425T
T ≈ 33.9°C
(A) Water (B) Sand (C) Same (D) None
Ans: A (water = 4200 J/kg°C, sand ≈ 800 J/kg°C. Sea stays cool during day, warm at night)
(A) J/kg (B) J/°C (C) J/kg°C (D) J/g°C
Ans: C (Joule per kilogram per degree Celsius)
(A) 168 kJ (B) 168 J (C) 4200 J (D) 84 kJ
Ans: A (Q = 2 × 4200 × 20 = 168,000 J = 168 kJ)
7) Latent Heat
Latent heat is the heat absorbed or released when a substance changes its state (solid ⇌ liquid ⇌ gas) without changing its temperature.
Q = m × L
Q = heat energy (J or cal)
m = mass (kg or g)
L = latent heat (J/kg or cal/g)
| Type | Symbol | Process | Definition | Value (water) |
|---|---|---|---|---|
| Latent heat of Fusion | Lf | Solid ↔ Liquid | Heat to melt 1 kg of ice at 0°C → water at 0°C (or freeze reverse) | 3.36 × 10⁵ J/kg = 336 kJ/kg = 80 cal/g |
| Latent heat of Vaporization | Lv | Liquid ↔ Gas | Heat to boil 1 kg of water at 100°C → steam at 100°C (or condense reverse) | 22.6 × 10⁵ J/kg = 2260 kJ/kg = 540 cal/g |
During phase change, temperature does NOT change. All the heat energy goes into breaking the intermolecular bonds (to separate molecules) rather than increasing kinetic energy.
• Melting: heat breaks the crystal lattice bonds
• Boiling: heat overcomes the intermolecular attractive forces completely
• Lv > Lf because gas molecules are completely separated (much more energy needed)
Q = m × Lf = 2 × 3.36 × 10⁵ = 6.72 × 10⁵ J = 672 kJ
Q = m × Lv = 0.5 × 22.6 × 10⁵ = 11.3 × 10⁵ J = 1.13 × 10⁶ J
(A) Increases (B) Decreases (C) Remains constant (D) First increases then decreases
Ans: C (heat is used to break bonds, not raise temperature — latent heat)
(A) 336 J/kg (B) 3360 J/kg (C) 3.36 × 10⁵ J/kg (D) 22.6 × 10⁵ J/kg
Ans: C (Lf = 3.36 × 10⁵ J/kg = 336 kJ/kg)
(A) Ice is colder (B) Ice absorbs latent heat to melt (C) Ice is denser (D) None
Ans: B (ice absorbs Lf = 336 kJ/kg while melting, providing extra cooling)
8) Evaporation vs Boiling
Both evaporation and boiling involve conversion of liquid to vapour, but they are DIFFERENT processes.
| Basis | Evaporation | Boiling |
|---|---|---|
| Definition | Surface phenomenon — liquid changes to vapour at the surface | Bulk phenomenon — liquid changes to vapour throughout the liquid |
| Temperature | Occurs at any temperature below boiling point | Occurs at a fixed temperature (boiling point) |
| Where it happens | Only at the surface of the liquid | Throughout the entire volume of the liquid (bubbles form) |
| Speed | Slow process | Fast process |
| Effect of pressure | Increases with wind speed, surface area, temperature | Boiling point increases with external pressure |
| Cooling effect | Causes cooling (molecules with higher KE escape → avg KE decreases) | No significant cooling of remaining liquid |
| Examples | Drying of clothes, sweat evaporating from skin, water cycle | Water boiling for tea, cooking rice |
Factors Affecting Rate of Evaporation
- Temperature: Higher temperature → faster evaporation (more molecules have enough KE to escape)
- Surface area: Larger surface area → faster evaporation (more molecules at surface)
- Wind speed: Higher wind → faster evaporation (removes vapour from surface → maintains concentration gradient)
- Humidity: Lower humidity → faster evaporation (air can hold more water vapour)
- Nature of liquid: More volatile liquids (alcohol, petrol) evaporate faster than less volatile ones (water, oil)
• When you sweat, water evaporates from your skin → takes away latent heat of vaporization from your body → you feel cool
• Desert coolers (evaporative coolers) work on this principle — water evaporates, cooling the air
• Interesting fact: Alcohol evaporates faster than water → it feels colder when rubbed on skin because it takes away heat faster!
(A) Heat is absorbed from surroundings (B) Heat is released (C) Temperature increases (D) Vapour is hot
Ans: A (molecules with higher KE escape → remaining molecules have lower avg KE → cooling)
9) Heat Transfer — Conduction, Convection & Radiation ⭐
Heat can be transferred in three ways — conduction, convection, and radiation. Understanding their differences is crucial for AMU.
| Property | Conduction | Convection | Radiation |
|---|---|---|---|
| Medium required | Yes (solids best) | Yes (liquids & gases) | No (vacuum also works) |
| Mechanism | Molecular vibrations + electron flow — molecules vibrate and pass energy to neighbours. No bulk movement. | Physical movement of molecules — hot fluid rises (expands → less dense), cool fluid sinks → convection currents | Electromagnetic waves (infrared radiation) — travels at speed of light |
| Speed | Slow | Moderate | Fastest (speed of light: 3×10⁸ m/s) |
| Example | Iron rod getting hot at one end when other end is in fire Hand on a hot pan |
Boiling water (convection currents) Sea breeze, land breeze AC placement (above → cool air sinks) |
Sun's heat reaching Earth Campfire warmth Heat from a room heater (infrared) |
| Depends on | Thermal conductivity (k), area, temp difference, thickness | Density differences, gravity, fluid properties | Temperature, surface area, nature of surface (colour, texture) |
A. Conduction — Detailed
Thermal conductivity (k): A measure of how well a material conducts heat. Units: W/mK or W/m°C.
Q/t = k × A × (T₁ − T₂) / d
Q/t = rate of heat transfer (W or J/s)
k = thermal conductivity of material
A = cross-sectional area, d = thickness
T₁ − T₂ = temperature difference
| Good Conductors | k (W/mK) | Bad Conductors (Insulators) | k (W/mK) |
|---|---|---|---|
| Silver | 430 | Wood | 0.1–0.2 |
| Copper | 390 | Rubber | 0.15 |
| Gold | 310 | Glass wool | 0.04 |
| Aluminium | 210 | Air | 0.025 |
| Iron | 80 | Plastic | 0.2 |
• Good conductors → used where heat needs to flow quickly: Cooking utensils (Cu/Al bottom), engine radiators (Cu), heat sinks in electronics (Al)
• Bad conductors → used where heat needs to be trapped/prevented: Cooking utensil handles (wood/plastic), ice box walls (glass wool), winter clothes (wool — traps air), house insulation (glass wool, foam)
• Why do woollen clothes keep us warm? Wool traps a layer of air. Air is a bad conductor → body heat can't escape → we stay warm. (Wool does NOT give heat!)
Q/t = k × A × ΔT / d
= 390 × 0.01 × 100 / 0.5
= 390 × 0.01 × 200
= 780 W (Joules per second)
B. Convection — Detailed
Convection occurs in fluids (liquids and gases). It involves actual movement of molecules.
| Type | Mechanism | Examples |
|---|---|---|
| Natural (Free) Convection | Fluid moves due to density differences caused by temperature gradients — gravity driven. No external force. | Sea breeze, land breeze Hot air rising from a radiator Boiling water (water at bottom gets hot → rises → cools → sinks) |
| Forced Convection | Fluid is forced to move by an external agent (fan, pump, blower) | Ceiling fan (circulates air) Car radiator with fan CPU cooling fan Air conditioner blower |
Sea Breeze & Land Breeze — Complete Explanation
- Day (Sea Breeze):
- Land heats up faster than sea water (land has low specific heat, water has high specific heat)
- Air above land becomes hot → expands → rises (density decreases)
- Cool air from above the sea rushes in towards the land to replace the rising hot air
- This cool wind from sea to land is called sea breeze
- Night (Land Breeze):
- Land cools down faster than sea water at night
- Air above the sea is now warmer (water cools slowly) → rises
- Cool air from the land rushes towards the sea
- This cool wind from land to sea is called land breeze
• Air conditioner (AC) is placed high on the wall — cool air is denser → sinks → cools the room from top to bottom
• Room heater is placed near the floor — hot air is less dense → rises → heats the room from bottom to top
• 🔥 This is a VERY common AMU MCQ!
C. Radiation — Detailed
- Radiation does NOT require any medium — it can travel through vacuum
- It travels as electromagnetic waves (primarily infrared, also visible and UV for very hot objects)
- All objects emit radiation — hotter objects emit more radiation and at shorter wavelengths
- A black body is a perfect absorber and perfect emitter of radiation
Good absorbers of radiation are also good emitters
A black surface that absorbs all radiation also emits radiation efficiently
A polished/shiny surface that reflects radiation is a poor emitter
| Application | Explanation |
|---|---|
| Black car gets hotter in summer | Black absorbs more radiation (good absorber) → gets hotter than a white car |
| White/light coloured clothes in summer | White reflects radiation (poor absorber) → keeps you cool |
| Dark coloured clothes in winter | Dark absorbs radiation (good absorber) → keeps you warm |
| Solar water heater has black painted surface | Black absorbs maximum solar radiation → heats water efficiently |
| Cooking utensils have polished/ shiny outer surface | Polished surface is poor radiator → keeps heat inside the utensil |
| Greenhouse effect | Glass lets sunlight in (visible light) but traps infrared radiation → inside gets hot |
Dull, rough, dark surfaces → good absorbers AND good emitters (radiators)
Shiny, smooth, light surfaces → poor absorbers AND poor emitters (good reflectors)
(A) Iron (B) Silver (C) Copper (D) Aluminium
Ans: B (silver has highest thermal conductivity: 430 W/mK)
(A) Conduction (B) Convection (C) Radiation (D) Both A & B
Ans: C (radiation — no medium needed for vacuum)
(A) Hot air rises (B) Hot air sinks (C) Radiation works better (D) Conduction is faster
Ans: A (hot air is less dense → rises → heats the room by convection)
(A) Conduction (B) Convection (C) Evaporation (D) Radiation
Ans: C (evaporation of water absorbs latent heat → cools the air)
10) PYQ Battle — 18 AMU Past Questions on Heat
(A) Kelvin (B) Celsius (C) Joule (D) Watt
Ans: C
(A) 100°F (B) 180°F (C) 212°F (D) 273°F
Ans: C (100 × 9/5 + 32 = 212)
(A) 0 K (B) 100 K (C) 273 K (D) 373 K
Ans: C
(A) 0°C (B) −100°C (C) −273°C (D) −200°C
Ans: C
(A) Water (B) Sand (C) Same (D) None
Ans: A (water = 4200, sand ≈ 800 J/kg°C)
(A) J/kg (B) J/°C (C) J/kg°C (D) J/g°C
Ans: C
(A) Increases (B) Decreases (C) Remains constant (D) First increases then decreases
Ans: C (latent heat)
(A) 336 J/kg (B) 3360 J/kg (C) 3.36 × 10⁵ J/kg (D) 22.6 × 10⁵ J/kg
Ans: C
(A) 0°C (B) 4°C (C) 100°C (D) −4°C
Ans: B (anomalous expansion of water)
(A) Iron (B) Silver (C) Copper (D) Aluminium
Ans: B
(A) Conduction (B) Convection (C) Radiation (D) Both A & B
Ans: C
(A) Hot air rises (B) Hot air sinks (C) Radiation is better (D) Conduction is faster
Ans: A
(A) α (B) 2α (C) 3α (D) α/3
Ans: C
(A) Thermometer (B) Thermostat (C) Barometer (D) Manometer
Ans: B
(A) Heat is absorbed (B) Heat is released (C) Temp increases (D) Vapour is hot
Ans: A
(A) Ice conducts heat (B) Ice insulates (C) Fish hibernate (D) Bottom water is 0°C
Ans: B (ice layer insulates → water below at ~4°C)
Ans: F = (−40 × 9/5) + 32 = −72 + 32 = −40°F (coincident point!)
Ans: Q = 2 × 4200 × 20 = 168,000 J = 168 kJ
(A) Conduction (B) Convection (C) Radiation (D) Refraction
Ans: D (refraction is for light, not heat transfer)
(A) All three modes (B) Only conduction (C) Only radiation (D) Only convection
Ans: A — vacuum stops conduction & convection, silvered walls reflect radiation
(A) Iron (B) Copper (C) Water (D) Aluminium
Ans: C (water = 4200 J/kg°C, much higher than metals)
(A) Conduction (B) Convection (C) Radiation (D) Evaporation
Ans: C
Ans: Q/t ∝ A → ratio = 1:2
11) Heating Curve of Ice — Complete State Change Graph ⭐
The heating curve of ice is a graph of temperature vs time when a block of ice at sub-zero temperature is heated continuously until it becomes steam. This is a FAVOURITE AMU topic!
Stage A→B: Ice at −20°C → 0°C (Q = m c_ice ΔT, no state change)
Stage B→C: Ice at 0°C melts → water at 0°C (Q = m Lf, temp constant)
Stage C→D: Water at 0°C → 100°C (Q = m c_water ΔT, no state change)
Stage D→E: Water at 100°C boils → steam at 100°C (Q = m Lv, temp constant)
Stage E→F: Steam at 100°C → above (Q = m c_steam ΔT, if continued)
| Stage | Change | Temp | Formula | Heat type |
|---|---|---|---|---|
| A→B | Ice warming | −20°C → 0°C | Q = mcΔT (c_ice = 2100) | Sensible |
| B→C | Ice → Water (melting) | 0°C constant | Q = mLf | Latent (fusion) |
| C→D | Water warming | 0°C → 100°C | Q = mcΔT (c_water = 4200) | Sensible |
| D→E | Water → Steam (boiling) | 100°C constant | Q = mLv | Latent (vaporization) |
| E→F | Steam heating | 100°C → higher | Q = mcΔT (c_steam ≈ 2000) | Sensible |
During melting (B→C) and boiling (D→E), temperature DOES NOT RISE. All the heat supplied is used to break intermolecular bonds (latent heat). No increase in kinetic energy → no temperature increase. The flat regions in the graph are called plateaus or temperature arrest points.
(A) A→B only (B) B→C and D→E (C) C→D only (D) E→F only
Ans: B (melting and boiling — latent heat stages)
12) Practice Problems — 23 Numericals with Step-by-Step Solutions
C = (104 − 32) × 5/9 = 72 × 5/9 = 40°C
K = 50 + 273 = 323 K
C = 400 − 273 = 127°C
F = (127 × 9/5) + 32 = 228.6 + 32 = 260.6°F
Q = m c ΔT = 5 × 450 × (75 − 25) = 5 × 450 × 50 = 112,500 J
Let T = final temp
300 × (60 − T) = 200 × (T − 20)
18000 − 300T = 200T − 4000
22000 = 500T
T = 44°C
2(90 − T) = 3(T − 10)
180 − 2T = 3T − 30
210 = 5T
T = 42°C
0.2 × 390 × (150 − T) = 0.5 × 4200 × (T − 25)
78(150 − T) = 2100(T − 25)
11700 − 78T = 2100T − 52500
64200 = 2178T
T ≈ 29.5°C
Q = m × Lf = 0.5 × 336 × 10³ = 168,000 J = 168 kJ
Q = 0.1 × 2260 × 10³ = 226,000 J
Step 1: Heat ice from −10°C to 0°C: Q₁ = 0.2 × 2100 × 10 = 4200 J
Step 2: Melt ice at 0°C: Q₂ = 0.2 × 336 × 10³ = 67,200 J
Step 3: Heat water from 0°C to 100°C: Q₃ = 0.2 × 4200 × 100 = 84,000 J
Step 4: Boil water at 100°C: Q₄ = 0.2 × 2260 × 10³ = 452,000 J
Total = 4200 + 67,200 + 84,000 + 452,000 = 607,400 J
ΔL = α L₀ ΔT = 1.2 × 10⁻⁵ × 5 × 40 = 2.4 × 10⁻³ m = 2.4 mm
L = 5 + 0.0024 = 5.0024 m
ΔL = 2.0034 − 2 = 0.0034 m
ΔT = ΔL / (α L₀) = 0.0034 / (1.7×10⁻⁵ × 2) = 0.0034 / 3.4×10⁻⁵ = 100°C
T = 30 + 100 = 130°C
Q/t = k A ΔT / d = 0.8 × 2 × 20 / 0.004 = 8000 W
Heat available from water cooling to 0°C: Q_w = 1 × 4200 × 30 = 126,000 J
Heat needed to melt ice: Q_ice = 1 × 336,000 = 336,000 J
Since Q_w < Q_ice, not all ice melts. Final temp = 0°C (mixture of ice + water)
Mass of ice melted = Q_w / Lf = 126,000 / 336,000 = 0.375 kg
Q/t = 390 × 0.005 × 100 / 0.4 = 390 × 0.005 × 250 = 487.5 W
C = (98.6 − 32) × 5/9 = 66.6 × 5/9 = 37°C
Heat absorbed = 0.8 × 1000 × 6 = 4800 W = 4800 J/s
4(80 − T) = 2(T − 20)
320 − 4T = 2T − 40
360 = 6T
T = 60°C
Heat exchanged = 4 × 4200 × (80 − 60) = 4 × 4200 × 20 = 336,000 J
ΔL = α L₀ ΔT = 1.2 × 10⁻⁵ × 100 × 30
= 1.2 × 10⁻⁵ × 3000 = 0.036 m = 3.6 cm
Apparent expansion of mercury = γ_mercury − γ_glass
= 1.8 × 10⁻⁴ − 0.25 × 10⁻⁴ = 1.55 × 10⁻⁴ K⁻¹
Overflow = V₀ × γ_app × ΔT = 500 × 1.55 × 10⁻⁴ × 40
= 500 × 6.2 × 10⁻³ = 3.1 ml
Heat lost by water = m_w × c_w × ΔT = 0.5 × 4200 × 30 = 63,000 J
Heat gained by ice to melt = m_ice × Lf
m_ice = 63,000 / 336,000 = 0.1875 kg = 187.5 g
Q = m c ΔT = 2 × 4200 × 60 = 504,000 J
Power = Q / t = 504,000 / (5 × 60) = 504,000 / 300 = 1680 W
Q/t = k A ΔT / d = 0.8 × 3 × 20 / 0.005 = 9600 W = 9600 J/s
Q per hour = 9600 × 3600 = 34.56 × 10⁶ J = 34.56 MJ
13) Greenhouse Effect — Detailed
The greenhouse effect is the process by which the Earth's atmosphere traps heat from the Sun, keeping the planet warm enough for life to exist.
Mechanism:
- Sunlight (visible light + UV) passes through the atmosphere and reaches Earth's surface
- The Earth absorbs this radiation and re-emits it as infrared radiation (heat)
- Greenhouse gases (CO₂, CH₄, H₂O vapour) in the atmosphere absorb infrared radiation and re-radiate it back towards Earth
- This traps heat in the atmosphere → Earth stays warm (avg ~15°C instead of −18°C without greenhouse effect)
| Greenhouse Gas | Source | Contribution |
|---|---|---|
| CO₂ | Burning fossil fuels, deforestation | ~60% |
| CH₄ (Methane) | Agriculture, livestock, landfills | ~20% |
| H₂O vapour | Natural (evaporation) | ~10% |
| CFCs | Refrigerants, aerosols | ~10% |
• Natural greenhouse effect — essential for life (keeps Earth warm)
• Enhanced greenhouse effect — human activities increase greenhouse gases → global warming (melting glaciers, rising sea levels, climate change)
• Glass in a greenhouse/ car: Glass lets visible light in, but traps infrared → inside gets hot (same principle as Earth's atmosphere)
(A) CO₂ (B) O₂ (C) N₂ (D) H₂
Ans: A
14) Thermal Expansion in Liquids — Apparent vs Real Expansion
When a liquid is heated in a container, both the liquid AND the container expand. What we observe is the apparent expansion of the liquid (the net effect).
γreal = γapparent + γcontainer
γreal = actual expansion coefficient of liquid
γapparent = what we observe (rise in container)
γcontainer = expansion coefficient of the container material (≈ 3α_solid)
• For liquids: γ_real is always greater than γ_apparent because the container also expands
• Water is ANOMALOUS in expansion behavior (explained in section 5)
• For gases: all gases have nearly the same γ ≈ 1/273 K⁻¹ (Charles' law)
15) Common Mistakes ❌ — Don't Lose Marks!
✅ Fix: Heat is energy (J). Temperature is measure of avg KE (K). Different concepts!
✅ Fix: For ΔT (temperature DIFFERENCE), °C and K are same magnitude. But absolute temperatures must be in K for gas laws. For specific heat: ΔT in °C is fine since 1°C = 1 K.
✅ Fix: Always convert grams to kg: mass in kg, c in J/kg°C, Q in J. If using g: c in J/g°C, Q in J. Stay consistent!
✅ Fix: Temperature is CONSTANT during melting/boiling. All heat is used as latent heat (breaking bonds).
✅ Fix: Conduction = solids (no movement of material). Convection = fluids (movement of material). Radiation = vacuum (EM waves).
✅ Fix: Sun's heat reaches Earth via radiation through vacuum. Only mode that works without medium.
✅ Fix: Good conductors (metals) ≠ good radiators. Dull black surfaces are good radiators, shiny surfaces are poor radiators.
✅ Fix: β = 2α (2D), γ = 3α (3D). Easy: linear → 1 coefficient, area → 2×, volume → 3×.
✅ Fix: Most substances expand when heated, contract when cooled. Water is ANOMALOUS between 0°C–4°C (contracts when heated).
✅ Fix: When ice goes to steam: heat ice to 0°C + melt ice + heat water to 100°C + boil water. Each step has its own formula!
16) Quick Revision — One-Liners
- Heat = energy (J). Temperature = avg KE of molecules (K, °C, °F)
- F = C × 9/5 + 32 and K = C + 273 — memorize cold
- C/100 = (F−32)/180 = (K−273)/100 — the universal conversion formula
- −40°C = −40°F — the only temperature where both scales agree
- Absolute zero = 0 K = −273.15°C — lowest possible temperature
- Q = mcΔT — heat when temperature changes (specific heat)
- Q = mL — heat during phase change (latent heat)
- Water c = 4200 J/kg°C — highest among common substances
- Lf (ice) = 336 kJ/kg — heat to melt ice at 0°C
- Lv (water) = 2260 kJ/kg — heat to boil water at 100°C
- Calorimetry: Heat lost = Heat gained (m₁c₁ΔT₁ = m₂c₂ΔT₂)
- Thermal expansion: ΔL = αL₀ΔT, β = 2α, γ = 3α
- Anomalous expansion of water: Max density at 4°C. Ice floats → lakes freeze from top
- Conduction: solids, molecular vibration. Convection: fluids, mass movement. Radiation: EM waves, no medium
- Good conductors: Silver > Copper > Gold > Aluminium > Iron
- Insulators: Wood, plastic, rubber, air, glass wool, wool
- Sea breeze (day): cool air from sea → land. Land breeze (night): cool air from land → sea
- AC high (sinks cool air): Heater low (rises hot air) — convection
- Black body: Perfect absorber = perfect emitter (Kirchhoff's law)
- Evaporation: Cools (surface phenomenon, any temp). Boiling: Bulk phenomenon, fixed temp
- Evaporation factors: Temp↑, Area↑, Wind↑, Humidity↓ → all increase evaporation